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2Physics Quote:
"Many of the molecules found by ROSINA DFMS in the coma of comet 67P are compatible with the idea that comets delivered key molecules for prebiotic chemistry throughout the solar system and in particular to the early Earth increasing drastically the concentration of life-related chemicals by impact on a closed water body. The fact that glycine was most probably formed on dust grains in the presolar stage also makes these molecules somehow universal, which means that what happened in the solar system could probably happen elsewhere in the Universe."
-- Kathrin Altwegg and the ROSINA Team

(Read Full Article: "Glycine, an Amino Acid and Other Prebiotic Molecules in Comet 67P/Churyumov-Gerasimenko"

Sunday, June 13, 2010

Glimpse of Heavy Electrons Reveals “Hidden Order”

J.C. Séamus Davis (Photo courtesy: Cornell University)

Using a microscope designed to image the arrangement and interactions of electrons in crystals, scientists have captured the first images of electrons that appear to take on extraordinary mass under certain extreme conditions. The technique reveals the origin of an unusual electronic phase transition in one particular material, and opens the door to further explorations of the properties and functions of so-called heavy fermions. Scientists from the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory, McMaster University, and Los Alamos National Laboratory describe the results in the June 3, 2010, issue of Nature.

“Physicists have been interested in the ‘problem’ of heavy fermions — why these electrons act as if they are hundreds or thousands of times more massive under certain conditions — for thirty or forty years,” said study leader Séamus Davis, a physicist at Brookhaven and the J.D. White Distinguished Professor of Physical Sciences at Cornell University. Understanding heavy fermion behavior could lead to the design of new materials for high-temperature superconductors.

In the current study, the scientists were imaging electronic properties in a material composed of uranium, ruthenium, and silicon that itself has been the subject of a 25-year scientific mystery. In this material — synthesized by Graeme Luke’s group at McMaster — the effects of heavy fermions begin to appear as the material is cooled below 55 kelvin (-218 °C). Then, an even more unusual electronic phase transition occurs below 17.5K.

[Image courtesy: Los Alamos National Laboratory] Spectroscopic imaging scanning tunneling microscopy reveals a "hidden order" of electrons, seen as bright areas, within uranium ruthenium silicate as it is cooled to very low temperatures. Seeing this hidden order for the first time has unraveled a 25-year-old physics mystery.

Scientists had attributed this lower-temperature phase transition to some form of “hidden order.” They could not distinguish whether it was related to the collective behavior of electrons acting as a wave, or interactions of individual electrons with the uranium atoms. Alexander Balatsky, a Los Alamos theoretical physicist at the Center for Integrated Nanotechnologies, provided guidance on how to examine this problem.

With that guidance, Davis’ group used a technique they’d designed to visualize the behavior of electrons to “see” what the electrons were doing as they passed through the mysterious phase transition. The technique, spectroscopic imaging scanning tunneling microscopy (SI-STM), measures the wavelength of electrons on the surface of the material in relation to their energy.

“Imagine flying over a body of water where standing waves are moving up and down, but not propagating toward the shore,” said Davis. “When you pass over high points, you can touch the water; over low points, you can’t. This is similar to what our microscope does. It images how many electrons can jump to the tip of our probe at every point on the surface.”

From the wavelength and energy measurements, the scientists can calculate the effective electron mass.

[Image credit: Mohammad Hamidian/Davis Lab, Cornell University] In this schematic diagram, individual electrons (white spheres) interact with uranium atoms (shown as yellow and blue f-electron orbitals of the uranium atoms) as they move through the URu2Si2 crystal. These interactions drastically inhibit the progress of the electrons, making them appear to take on extraordinary mass – an effect imaged for the first time in this study.

“This technique reveals that we are dealing with very heavy electrons — or electrons that act as if they are extremely heavy because they are somehow being slowed down,” Davis said.

The detection of “heavy electron” characteristics below the second transition temperature provides direct experimental evidence that the electrons are interacting with the uranium atoms rather than acting as a wave.

To visualize this, imagine a team of football players running up the field after a kickoff. If each player were free to run unimpeded, the whole team would appear to operate as a wave of relatively independent “electrons.” But imagine instead that the field is strewn with an array of chairs, and each player has to sit for an instant every time he encounters a chair before continuing up the field. In this case the chairs are analogous to the uranium atoms. Those interactions between players and chairs (or electrons and uranium atoms) clearly slow the progress.

In the case of the uranium material, the electron slowdown lasts only a tiny fraction of a second at each uranium atom. But because kinetic energy and mass are mathematically related, the slowdown makes it appear as if the electrons are more massive than a free electron.

Besides revealing these interactions as the source of “hidden order” in the uranium compound, Davis’ study shows that the SI-STM technique can be used to visualize heavy electrons. That in turn opens the door to more ways to investigate and visualize this phenomenon.

The research team is continuing to probe a variety of related compounds with this new approach to further their understanding of heavy fermion systems.

“Heavy fermions remain mysterious in many ways, and it’s our job as scientists to solve the problem,” Davis said.

A. R. Schmidt,M. H. Hamidian,P. Wahl,F. Meier,A. V. Balatsky,J. D. Garrett,T. J. Williams,G. M. Luke& J. C. Davis, "Imaging the Fano lattice to ‘hidden order’ transition in URu2Si2", Nature, Vol 465, pp 570–576 (03 June 2010). Abstract.

[We thank Brookhaven National Laboratory for materials used in this posting]

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